Issue 12, 2015
From the journal:

Organic Chemistry Frontiers

Regioselective palladium(ii)-catalyzed aerobic oxidative Heck-type C3 alkenylation of sulfocoumarins†

Namhoon Kim,ab   Minsik Minab  and  Sungwoo Hong*ab  

* Corresponding authors

a Department of Chemistry, Korea Advanced Institute of Science and Technology, Daejeon, Korea
E-mail: hongorg@kaist.ac.kr

b Center for Catalytic Hydrocarbon Functionalization, Institute for Basic Science (IBS), Daejeon, Korea

Abstract

An efficient method for the direct C–H olefination of sulfocoumarins with a wide range of alkenes is developed. Moreover, O2 was successfully utilized as the sole oxidant for the oxidative Heck reaction. This approach enables the rapid generation of various 3-alkenylated sulfocoumarins.

Graphical abstract: Regioselective palladium(ii)-catalyzed aerobic oxidative Heck-type C3 alkenylation of sulfocoumarins

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C5QO00294J
Article type
Research Article
Submitted
22 Way 2015
Accepted
26 Dit 2015
First published
28 Dit 2015

Org. Chem. Front., 2015,2, 1621-1624

Author version available

Download author version (PDF)

Permissions

Request permissions

Regioselective palladium(II)-catalyzed aerobic oxidative Heck-type C3 alkenylation of sulfocoumarins

N. Kim, M. Min and S. Hong, Org. Chem. Front., 2015, 2, 1621 DOI: 10.1039/C5QO00294J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements