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We have developed porous carbons with various pore sizes from porous coordination polymers (PCPs) with Mg2+ and benzene carboxylate linkers. The pore sizes of the porous carbons were tuned systematically according to the dimensionality of inorganic building blocks and the metal–oxygen–metal connectivity of the PCP frameworks.

Graphical abstract: Control of pore distribution of porous carbons derived from Mg2+ porous coordination polymers

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