Issue 25, 2014

Study of a magnetic-cooling material Gd(OH)CO3

Abstract

The magnetocaloric effect of a coordination polymeric material with a repeating unit of Gd(OH)CO3 has been studied experimentally using isothermal magnetization and heat capacity measurements. The maximum entropy change, −ΔSm, reaches 66.4 J kg−1 K−1 or 355 mJ cm−3 K−1 for ΔH = 7 T and T = 1.8 K. Density functional theory (DFT) calculations show weak and competing antiferromagnetic interactions between the metal centres.

Graphical abstract: Study of a magnetic-cooling material Gd(OH)CO3

Supplementary files

Article information

Article type
Paper
Submitted
04 Agd 2014
Accepted
30 Agd 2014
First published
01 Cax 2014

J. Mater. Chem. A, 2014,2, 9851-9858

Author version available

Study of a magnetic-cooling material Gd(OH)CO3

Y. Chen, L. Qin, Z. Meng, D. Yang, C. Wu, Z. Fu, Y. Zheng, J. Liu, R. Tarasenko, M. Orendáč, J. Prokleška, V. Sechovský and M. Tong, J. Mater. Chem. A, 2014, 2, 9851 DOI: 10.1039/C4TA01646G

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