Issue 80, 2014

Affecting surface chirality via multicomponent adsorption of chiral and achiral molecules

Abstract

Here we report on the apparent reduction in surface chirality upon co-assembling a chiral and achiral molecule into a physisorbed self-assembled monolayer at the liquid/solid interface as revealed by scanning tunneling microscopy (STM). Chiral OPV with achiral thymine gives rise to surface-confined supramolecular diastereomers.

Graphical abstract: Affecting surface chirality via multicomponent adsorption of chiral and achiral molecules

Supplementary files

Article information

Article type
Communication
Submitted
09 Qas 2014
Accepted
18 Leq 2014
First published
26 Leq 2014

Chem. Commun., 2014,50, 11903-11906

Author version available

Affecting surface chirality via multicomponent adsorption of chiral and achiral molecules

Z. Guo, I. De Cat, B. Van Averbeke, J. Lin, G. Wang, H. Xu, R. Lazzaroni, D. Beljonne, A. P. H. J. Schenning and S. De Feyter, Chem. Commun., 2014, 50, 11903 DOI: 10.1039/C4CC04393F

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