Issue 19, 2014

Synthesis, structure and reactivity of FeII/III–NH3 complexes bearing a tripodal sulfonamido ligand

Abstract

Complexes [MnMST(NH3)]n−3 (Mn = FeII, FeIII, GaIII) were prepared and each contains an intramolecular hydrogen bonding network involving the ammonia ligand. Deprotonation of the FeIII–NH3 complex afforded a putative [FeIIIMST(NH2)] species whose reactivity has been explored.

Graphical abstract: Synthesis, structure and reactivity of FeII/III–NH3 complexes bearing a tripodal sulfonamido ligand

Supplementary files

Article information

Article type
Communication
Submitted
19 Xim 2013
Accepted
09 Qun 2014
First published
10 Qun 2014

Chem. Commun., 2014,50, 2515-2517

Author version available

Synthesis, structure and reactivity of FeII/III–NH3 complexes bearing a tripodal sulfonamido ligand

N. S. Sickerman, S. M. Peterson, J. W. Ziller and A. S. Borovik, Chem. Commun., 2014, 50, 2515 DOI: 10.1039/C3CC48804G

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