Issue 95, 2013
From the journal:

Chemical Communications

Preparation and reactivity of a dinitrogen-bridged dimolybdenum-tetrachloride complex†

Kazuya Arashiba,a   Shogo Kuriyama,a   Kazunari Nakajimaa  and  Yoshiaki Nishibayashi*a  

* Corresponding authors

a Institute of Engineering Innovation, School of Engineering, The University of Tokyo, Yayoi, Bunkyo-ku, Tokyo, Japan
E-mail: ynishiba@sogo.t.u-tokyo.ac.jp
Fax: +81-3-5841-1175

Abstract

A dinitrogen-bridged dimolybdenum-tetrachloride complex is prepared and reduced with Super-Hydride (LiBHEt3) to afford the corresponding dimolybdenum-dinitrogen complex together with the formation of molecular dihydrogen. This reaction proceeds via the ligand exchange of the coordinated dihydrogen generated in situ with molecular dinitrogen.

Graphical abstract: Preparation and reactivity of a dinitrogen-bridged dimolybdenum-tetrachloride complex

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C3CC46946H
Article type
Communication
Submitted
11 Way 2013
Accepted
08 Dit 2013
First published
23 Dit 2013
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2013,49, 11215-11217

Permissions

Request permissions

Preparation and reactivity of a dinitrogen-bridged dimolybdenum-tetrachloride complex

K. Arashiba, S. Kuriyama, K. Nakajima and Y. Nishibayashi, Chem. Commun., 2013, 49, 11215 DOI: 10.1039/C3CC46946H

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements