Issue 39, 2013

Multicomponent self-sorting of a Pd7 molecular boat and its use in catalytic Knoevenagel condensation

Abstract

Unique three-component self-assembly of a cis-blocked 90° Pd(II) acceptor with a mixture of tri- and tetra-imidazole donors led to the self-sorting of a Pd7 molecular boat with an internal nanocavity, which catalyses the Knoevenagel condensation of a series of aromatic aldehydes with 1,3-dimethylbarbituric acid and Meldrum's acid in aqueous media.

Graphical abstract: Multicomponent self-sorting of a Pd7 molecular boat and its use in catalytic Knoevenagel condensation

Supplementary files

Article information

Article type
Communication
Submitted
09 Dit 2012
Accepted
17 Kax 2012
First published
18 Kax 2012

Chem. Commun., 2013,49, 4307-4309

Multicomponent self-sorting of a Pd7 molecular boat and its use in catalytic Knoevenagel condensation

D. Samanta and P. S. Mukherjee, Chem. Commun., 2013, 49, 4307 DOI: 10.1039/C2CC37377G

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