Issue 23, 2011

Emerging supramolecular synthons: C–H⋯π(chelate) interactions in metal bis(1,1-dithiolates)

Abstract

Crystal structures of transition and main group element 1,1-dithiolates are shown to be partially sustained by C–H⋯π(chelate) interactions. For the planar binary bisdithiocarbamates, C–H⋯π(MS2C) interactions lead to aggregation patterns ranging from a 0-D four molecule aggregate to a 3-D architecture but with the majority of structures featuring 1-D or 2-D supramolecular assemblies.

Graphical abstract: Emerging supramolecular synthons: C–H⋯π(chelate) interactions in metal bis(1,1-dithiolates)

Supplementary files

Article information

Article type
Communication
Submitted
28 Nah 2011
Accepted
13 Cig 2011
First published
01 Agd 2011

Chem. Commun., 2011,47, 6623-6625

Emerging supramolecular synthons: C–H⋯π(chelate) interactions in metal bis(1,1-dithiolates)

E. R. T. Tiekink and J. Zukerman-Schpector, Chem. Commun., 2011, 47, 6623 DOI: 10.1039/C1CC11173F

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