Issue 31, 2022

Synthesis of a Zr4(embonate)6–cobalt based superstructure for photocatalytic hydrogen production

Abstract

Herein, we report an efficient method to construct cage-based MOF materials with exposed metal active sites for catalysis. By employing Zr4L6 (L = embonate) cages as precursors for assembly with N-containing ligands and Co2+ ions, a new Zr4L6–Co based chain structure (PTC-318) has been generated through two-step reactions. Interestingly, in the absence of a photosensitizer, PTC-318 exhibits notable photocatalytic activity for H2 evolution under visible-light irradiation.

Graphical abstract: Synthesis of a Zr4(embonate)6–cobalt based superstructure for photocatalytic hydrogen production

Supplementary files

Article information

Article type
Communication
Submitted
22 Qas 2022
Accepted
08 Qad 2022
First published
09 Qad 2022

Dalton Trans., 2022,51, 11612-11616

Synthesis of a Zr4(embonate)6–cobalt based superstructure for photocatalytic hydrogen production

Q. Teng, Y. He, S. Chen and J. Zhang, Dalton Trans., 2022, 51, 11612 DOI: 10.1039/D2DT01976K

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