Gefei Li, Masato Noguchi, Genki Arisaka, Yuuki Tanaka and Shin-ichiro Shoda
Org. Biomol. Chem., 2021,19, 3134-3138
DOI:
10.1039/D1OB00311A,
Communication
The first protection/deprotection-free process for radical C-glycosylation has been achieved through one-step preparable glycosyl dithiocarbamates (GDTCs). The Giese-type reaction and radical allylation of unprotected GDTCs were successfully performed to obtain the corresponding α-C-glycosides stereoselectively under mild reaction conditions.