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Abstract | Cited by

Here, we present the first example of sp3 hybridized carbon centered (Csp3) tetrel bonding mediated 3D BODIPY assembly via the exceptional synergy of Csp3⋯N and Csp3⋯F pair interactions. The carbon tetrel bond interaction energies of Csp3⋯N and Csp3⋯F are amplified significantly as the size of the 1D chain grows from dimer to tetramer BODIPY units.

Graphical abstract: Carbon (sp3) tetrel bonding mediated BODIPY supramolecular assembly via unprecedented synergy of Csp3⋯N and Csp3⋯F pair interactions

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