Issue 12, 2020

A microporous metal–organic framework with naphthalene diimide groups for high methane storage

Abstract

We reported a microporous MOF FJU-101 with open naphthalene diimide functional groups for room temperature (RT) high methane storage. At RT and 65 bar, the total volumetric CH4 storage capacity of 212 cm3 (STP) cm−3 of FJU-101a is significantly higher than those of the isoreticular MFM-130a and UTSA-40a. The enhanced methane uptake in FJU-101a is attributed to the polar carbonyl sites, which can generate strong electrostatic interactions with CH4 molecules.

Graphical abstract: A microporous metal–organic framework with naphthalene diimide groups for high methane storage

Supplementary files

Article information

Article type
Communication
Submitted
08 Cax 2019
Accepted
25 Qas 2019
First published
25 Qas 2019

Dalton Trans., 2020,49, 3658-3661

A microporous metal–organic framework with naphthalene diimide groups for high methane storage

Y. Ye, R. Lin, H. Cui, A. Alsalme, W. Zhou, T. Yildirim, Z. Zhang, S. Xiang and B. Chen, Dalton Trans., 2020, 49, 3658 DOI: 10.1039/C9DT01911A

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