Issue 83, 2020
From the journal:

Chemical Communications

All-metal Baird aromaticity†

Dandan Chen, ORCID logo ab   Dariusz W. Szczepanik, ORCID logo bc   Jun Zhu ORCID logo *a  and  Miquel Solà ORCID logo *b  

* Corresponding authors

a State Key Laboratory of Physical Chemistry of Solid Surfaces and Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), Fujian Provincial Key Laboratory of Theoretical and Computational Chemistry and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, China
E-mail: jun.zhu@xmu.edu.cn

b Institute of Computational Chemistry and Catalysis and Department of Chemistry, University of Girona, C/M. Aurèlia Capmany 69, Girona, Catalonia, Spain
E-mail: miquel.sola@udg.edu

c K. Guminski Department of Theoretical Chemistry, Faculty of Chemistry, Jagiellonian University, Gronostajowa 2, Kraków 30-387, Poland

Abstract

Baird's rule has been applied to a large scope of organic molecular systems for rationalizing the aromaticity reversal in the lowest-lying triplet state. In this study, we demonstrate that Baird's rule can also be extended to all-metal systems with σ- and π-aromaticity.

Graphical abstract: All-metal Baird aromaticity

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Article information

DOI
https://doi.org/10.1039/D0CC05586G
Article type
Communication
Submitted
17 Leq 2020
Accepted
07 Way 2020
First published
07 Way 2020

Chem. Commun., 2020,56, 12522-12525

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All-metal Baird aromaticity

D. Chen, D. W. Szczepanik, J. Zhu and M. Solà, Chem. Commun., 2020, 56, 12522 DOI: 10.1039/D0CC05586G

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