Issue 39, 2019

Zirconium complexes supported by a ferrocene-based ligand as redox switches for hydroamination reactions

Abstract

The synthesis of (thiolfan*)Zr(NEt2)2 (thiolfan* = 1,1′-bis(2,4-di-tert-butyl-6-thiophenoxy)ferrocene) and its catalytic activity for intramolecular hydroamination are reported. In situ oxidation and reduction of the metal complex results in reactivity towards different substrates. The reduced form of (thiolfan*)Zr(NEt2)2 catalyzes hydroamination reactions of primary aminoalkenes, whereas the oxidized form catalyzes hydroamination reactions of secondary aminoalkenes.

Graphical abstract: Zirconium complexes supported by a ferrocene-based ligand as redox switches for hydroamination reactions

Supplementary files

Article information

Article type
Communication
Submitted
06 Nah 2019
Accepted
08 Agd 2019
First published
08 Agd 2019

Chem. Commun., 2019,55, 5587-5590

Author version available

Zirconium complexes supported by a ferrocene-based ligand as redox switches for hydroamination reactions

Y. Shen, S. M. Shepard, C. J. Reed and P. L. Diaconescu, Chem. Commun., 2019, 55, 5587 DOI: 10.1039/C9CC01076A

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