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This paper describes the first metal-free hydrogenation of 3,6-diarylpyridazines, which was successfully realized using B(C6F5)3 as a catalyst. A variety of 1,4,5,6-tetrahydropyridazine derivatives were furnished in 85–95% yields.

Graphical abstract: B(C6F5)3-catalyzed metal-free hydrogenation of 3,6-diarylpyridazines

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