Issue 58, 2016

Shedding light on an ultra-bright photoluminescent lamellar gold thiolate coordination polymer [Au(p-SPhCO2Me)]n

Abstract

The first structure elucidation of a lamellar gold thiolate coordination polymer is described. [Au(p-SPhCO2Me)]n is obtained from the simultaneous esterification of mercaptobenzoic acid and reduction of the Au(III) precursor. Despite the presence of aurophilic interactions, the intense phosphorescence (QY ∼ 70%) originates from intra-ligand and metal-to-ligand transitions.

Graphical abstract: Shedding light on an ultra-bright photoluminescent lamellar gold thiolate coordination polymer [Au(p-SPhCO2Me)]n

Supplementary files

Article information

Article type
Communication
Submitted
21 Kax 2015
Accepted
08 Nah 2016
First published
08 Nah 2016

Chem. Commun., 2016,52, 9063-9066

Shedding light on an ultra-bright photoluminescent lamellar gold thiolate coordination polymer [Au(p-SPhCO2Me)]n

C. Lavenn, N. Guillou, M. Monge, D. Podbevšek, G. Ledoux, A. Fateeva and A. Demessence, Chem. Commun., 2016, 52, 9063 DOI: 10.1039/C5CC10448C

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