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Rigid tetrahedral ligands are of particular interest in Metal–Organic Framework (MOF) construction due to their highly branched nature, high symmetry and also their rarity. Within this context the silicon-centred linker tetrakis(4-tetrazolylphenyl)silane is shown to give porous networks exhibiting fluorite or garnet topology with copper(II), manganese(II) and cadmium(II) metal based nodes.

Graphical abstract: Microporous metal–organic frameworks built from rigid tetrahedral tetrakis(4-tetrazolylphenyl)silane connectors

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