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Abstract | Cited by

Reductions of the β-diketiminato group 14 metal(II) chloride complexes, [(ButMesNacnac)ECl] (ButMesNacnac = [(MesNCBut)2CH]−; Mes = mesityl; E = Ge, Sn or Pb), with a magnesium(I) dimer have led to differing outcomes, which include the formation of the first β-diketiminato group 14 metal(I) dimer, [{(ButMesNacnac)Sn}2].

Graphical abstract: Contrasting reductions of group 14 metal(ii) chloride complexes: synthesis of a β-diketiminato tin(i) dimer

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