Issue 4, 2003
From the journal:

Chemical Communications

Liquid clathrate formation in ionic liquid–aromatic mixtures†

John D. Holbrey,a   W. Matthew Reichert,a   Mark Nieuwenhuyzen,b   Oonagh Sheppard,b   Christopher Hardacrebc  and  Robin D. Rogers*a  

* Corresponding authors

a Center for Green Manufacturing and Department of Chemistry, The University of Alabama, Tuscaloosa, AL 35487, USA
E-mail: rdrogers@bama.ua.edu

b Department of Chemistry and QUILL, Queen′s University of Belfast, Belfast, Northern Ireland, UK
E-mail: c.hardacre@qub.ac.uk

c QUILL, Queen′s University of Belfast, Belfast, Northern Ireland, UK
E-mail: c.hardacre@qub.ac.uk

Abstract

1-Alkyl-3-methylimidazolium containing ionic liquids with hexafluorophosphate, bis(trifyl)imide, tetrafluoroborate, and chloride anions form liquid clathrates when mixed with aromatic hydrocarbons; in the system 1,3-dimethylimidazolium hexafluorophosphate–benzene, the aromatic solute could be trapped in the solid state forming a crystalline 2∶1 inclusion compound.

Graphical abstract: Liquid clathrate formation in ionic liquid–aromatic mixtures

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Article information

DOI
https://doi.org/10.1039/B212726A
Article type
Communication
Submitted
21 Kax 2002
Accepted
02 Qun 2003
First published
21 Qun 2003

Chem. Commun., 2003, 476-477

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Liquid clathrate formation in ionic liquid–aromatic mixtures

J. D. Holbrey, W. M. Reichert, M. Nieuwenhuyzen, O. Sheppard, C. Hardacre and R. D. Rogers, Chem. Commun., 2003, 476 DOI: 10.1039/B212726A

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