Issue 11, 2014
From the journal:

Organic Chemistry Frontiers

Asymmetric cobalt catalysts for hydroboration of 1,1-disubstituted alkenes†

Jianhui Chen,a   Tuo Xi,a   Xiang Ren,a   Biao Cheng,a   Jun Guoa  and  Zhan Lu*a  

* Corresponding authors

a Department of Chemistry, Zhejiang University, 148 Tianmushan Road Hangzhou, Zhejiang, China
E-mail: luzhan@zju.edu.cn

Abstract

Chiral iminopyridine oxazoline (IPO) ligands were designed, synthesized and utilized for the first cobalt-catalyzed highly regio- and enantioselective anti-Markovnikov hydroboration of 1,1-disubstituted aryl alkenes. These novel IPO ligands will likely be of high value for asymmetric transformations with first-row transition metals.

Graphical abstract: Asymmetric cobalt catalysts for hydroboration of 1,1-disubstituted alkenes

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Article information

DOI
https://doi.org/10.1039/C4QO00295D
Article type
Research Article
Submitted
10 Nov 2014
Accepted
18 Nov 2014
First published
19 Nov 2014

Org. Chem. Front., 2014,1, 1306-1309

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Asymmetric cobalt catalysts for hydroboration of 1,1-disubstituted alkenes

J. Chen, T. Xi, X. Ren, B. Cheng, J. Guo and Z. Lu, Org. Chem. Front., 2014, 1, 1306 DOI: 10.1039/C4QO00295D

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