Is the unexpected behaviour of the resolved K3[CrIII(C2O4)3] in aqueous solution responsible for the formation of pure chiral solid phase of a two-dimensional (2D) [MnIICrIII(C2O4)3 NEt(n-Pr)(n-Bu)(n-C5H11)] network?

Michel  Gruselle; Cyrille  Train; Nikolai S. Ovanesyan; Viktor D. Makhaev; Christine  Cordier

doi:10.1070/MC2004v014n06ABEH002035

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Is the unexpected behaviour of the resolved K₃[Cr^III(C₂O₄)₃] in aqueous solution responsible for the formation of pure chiral solid phase of a two-dimensional (2D) [Mn^IICr^III(C₂O₄)₃ NEt(n-Pr)(n-Bu)(n-C₅H₁₁)] network?

Michel Gruselle,*^a Cyrille Train,^a Nikolai S. Ovanesyan,^b Viktor D. Makhaev^b and Christine Cordier^c

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* Corresponding authors

^a Laboratoire de Chimie Inorganique et Matériaux Moléculaires, CNRS, Université Pierre et Marie Curie, Paris, France, 4 place jussieu, case 42, cedex 05, Paris, France
E-mail: gruselle@ccr.jussieu.fr

^b Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation, Chernogolovka, Noginsky district, Moscow Region, Russian Federation

^c Itodys, UMR CNRS 7086, Université Paris 7 - Denis Diderot, Paris, France, 1 rue Guy de la Brosse, Paris, France

Abstract

Racemic and resolved [Cr^III(C₂O₄)₃]K₃ dissolved in water were investigated by IR spectroscopy. Compared to the racemic compound, the spectrum of the resolved one exhibits additional peaks, which have a complex temporal evolution. These peaks are attributed to water molecules coordinated to the metal ion and tentatively related to the formation of a pure chiral solid phase of two-dimensional (2D) oxalate-based Mn–Cr networks starting from partially resolved [Cr^III(C₂O₄)₃]^3–.

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DOI: https://doi.org/10.1070/MC2004v014n06ABEH002035
Article type: Communication
Submitted: 14 Sep 2004

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Mendeleev Commun., 2004,14, 284-285

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Is the unexpected behaviour of the resolved K₃[Cr^III(C₂O₄)₃] in aqueous solution responsible for the formation of pure chiral solid phase of a two-dimensional (2D) [Mn^IICr^III(C₂O₄)₃ NEt(n-Pr)(n-Bu)(n-C₅H₁₁)] network?

M. Gruselle, C. Train, N. S. Ovanesyan, V. D. Makhaev and C. Cordier, Mendeleev Commun., 2004, 14, 284 DOI: 10.1070/MC2004v014n06ABEH002035

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Mendeleev Communications

Is the unexpected behaviour of the resolved K₃[Cr^III(C₂O₄)₃] in aqueous solution responsible for the formation of pure chiral solid phase of a two-dimensional (2D) [Mn^IICr^III(C₂O₄)₃ NEt(n-Pr)(n-Bu)(n-C₅H₁₁)] network?

Abstract

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Is the unexpected behaviour of the resolved K₃[Cr^III(C₂O₄)₃] in aqueous solution responsible for the formation of pure chiral solid phase of a two-dimensional (2D) [Mn^IICr^III(C₂O₄)₃ NEt(n-Pr)(n-Bu)(n-C₅H₁₁)] network?

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