Issue 28, 2024

Recent advances in organic molecule reactions on metal surfaces

Abstract

Chemical reactions of organic molecules on metal surfaces have been intensively investigated in the past decades, where metals play the role of catalysts in many cases. In this review, first, we summarize recent works on spatial molecules, small H2O, O2, CO, CO2 molecules, and the molecules carrying silicon groups as the new trends of molecular candidates for on-surface chemistry applications. Then, we introduce spectroscopy and DFT study advances in on-surface reactions. Especially, in situ spectroscopy technologies, such as electron spectroscopy, force spectroscopy, X-ray photoemission spectroscopy, STM-induced luminescence, tip-enhanced Raman spectroscopy, temperature-programmed desorption spectroscopy, and infrared reflection adsorption spectroscopy, are important to confirm the occurrence of organic reactions and analyze the products. To understand the underlying mechanism, the DFT study provides detailed information about reaction pathways, conformational evolution, and organometallic intermediates. Usually, STM/nc-AFM topological images, in situ spectroscopy data, and DFT studies are combined to describe the mechanism behind on-surface organic reactions.

Graphical abstract: Recent advances in organic molecule reactions on metal surfaces

Article information

Article type
Review Article
Submitted
19 Dec 2023
Accepted
29 May 2024
First published
30 May 2024

Phys. Chem. Chem. Phys., 2024,26, 19052-19068

Recent advances in organic molecule reactions on metal surfaces

H. Gao, Phys. Chem. Chem. Phys., 2024, 26, 19052 DOI: 10.1039/D3CP06148E

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