A decanuclear [DyIII6ZnII4] cluster: a {ZnII4} rectangle surrounding an octahedral {DyIII6} single molecule magnet

Nikoleta Stavgianoudaki; Milosz Siczek; Tadeusz Lis; Giulia Lorusso; Marco Evangelisti; Constantinos J. Milios

doi:10.1039/C9DT00440H

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A decanuclear [Dy ^III₆Zn ^II₄] cluster: a {Zn ^II₄} rectangle surrounding an octahedral {Dy ^III₆} single molecule magnet†

Nikoleta Stavgianoudaki,^a Milosz Siczek,

^b Tadeusz Lis,^b Giulia Lorusso,

^c Marco Evangelisti

^c and Constantinos J. Milios

*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, The University of Crete, Voutes 71003, Herakleion, Greece
E-mail: komil@uoc.gr

^b Faculty of Chemistry, University of Wroclaw, Joliot-Curie 14, Wroclaw 50-383, Poland

^c Instituto de Ciencia de Materiales de Aragón (ICMA), CSIC – Universidad de Zaragoza, 50009 Zaragoza, Spain

Abstract

An octahedral {Dy^III₆} cage within a diamagnetic {Zn^II₄} rectangle is reported, with magnetic relaxation studies revealing single-molecule magnet behaviour for the complex under zero external dc field with U_eff = 43 K and τ_o = 1 × 10⁻⁵ s.

This article is part of the themed collection: Spotlight Collection focused on Inorganic Chemistry in Greece

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Article information

DOI: https://doi.org/10.1039/C9DT00440H
Article type: Communication
Submitted: 30 Jan 2019
Accepted: 18 Feb 2019
First published: 18 Feb 2019
This article is Open Access

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Dalton Trans., 2019,48, 3566-3570

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A decanuclear [Dy^III₆Zn^II₄] cluster: a {Zn^II₄} rectangle surrounding an octahedral {Dy^III₆} single molecule magnet

N. Stavgianoudaki, M. Siczek, T. Lis, G. Lorusso, M. Evangelisti and C. J. Milios, Dalton Trans., 2019, 48, 3566 DOI: 10.1039/C9DT00440H

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Dalton Transactions