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Issue 26, 2015
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Photocatalytic CO2 reduction by a mixed metal (Zr/Ti), mixed ligand metal–organic framework under visible light irradiation

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Abstract

Postsynthetic exchange (PSE) of Ti(IV) into a Zr(IV)-based MOF enabled photocatalytic CO2 reduction to HCOOH under visible light irradiation with the aid of BNAH and TEOA. Use of a mixed-ligand strategy enhanced the photocatalytic activity of the MOF by introducing new energy levels in the band structure of the MOF.

Graphical abstract: Photocatalytic CO2 reduction by a mixed metal (Zr/Ti), mixed ligand metal–organic framework under visible light irradiation

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Supplementary files

Article information


Submitted
24 Jan 2015
Accepted
18 Feb 2015
First published
18 Feb 2015

This article is Open Access

Chem. Commun., 2015,51, 5735-5738
Article type
Communication
Author version available

Photocatalytic CO2 reduction by a mixed metal (Zr/Ti), mixed ligand metal–organic framework under visible light irradiation

Y. Lee, S. Kim, J. K. Kang and S. M. Cohen, Chem. Commun., 2015, 51, 5735 DOI: 10.1039/C5CC00686D

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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