A clear cut variation from kinetic to thermodynamic control of products is observed for polyfluoroalkylation reactions of CF3CF2–, (CF3)2CF–, and (CF3)3C– with pentafluoropyridine and tetrafluoropyridazine.
R. D. Chambers, R. P. Corbally, M. Y. Gribble and W. K. R. Musgrave, J. Chem. Soc. D, 1971, 1345 DOI: 10.1039/C29710001345
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