The central sulphur atom of aliphatic trisulphides is removed with triphenylphosphine, whereas with tris(diethylamino)phosphine only the sulphur bonded to carbon is extruded.
D. N. Harpp and D. K. Ash, J. Chem. Soc. D, 1970, 811 DOI: 10.1039/C29700000811
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