Issue 2, 1981
From the journal:

Journal of the Chemical Society, Dalton Transactions

Kinetics and mechanism of the decomposition of [(NH2)2CSNO]+

Peter Collings,   Michael Garley  and  Geoffrey Stedman  

Abstract

The kinetics of decomposition of 2[(NH2)2CSNO]+ to [(NH2)2CSSC(NH2)2]2++ 2NO˙ have been studied spectrophotometrically in oxygen-free aqueous solutions. Reaction is inhibited by the product, nitrogen(II) monoxide, and the rate equation, based upon initial rates, takes the form shown below. The mechanism involves ν0=k1[CS(NH2)2][(NH2)2CSNO+]+k2[(NH2)2CSNO+]2 parallel pathways, one involving the reversible formation of a radical intermediate, [(NH2)2CSSC(NH2)2]+˙, while the other involves a bimolecular reaction between two molecules of [(NH2)2CSNO]+.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/DT9810000331
Article type
Paper

J. Chem. Soc., Dalton Trans., 1981, 331-335

Permissions

Request permissions

Kinetics and mechanism of the decomposition of [(NH2)2CSNO]+

P. Collings, M. Garley and G. Stedman, J. Chem. Soc., Dalton Trans., 1981, 331 DOI: 10.1039/DT9810000331

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements