Issue 64, 2024

Zirconium-based metal–organic frameworks and their roles in electrocatalysis

Abstract

Due to their exceptional chemical stability in water and high structural tunability, zirconium(IV)-based MOFs (Zr-MOFs) have been considered attractive materials in the broad fields of electrocatalysis. Numerous studies published since 2015 have attempted to utilise Zr-MOFs in electrocatalysis, with the porous framework serving as either the active electrocatalyst or the scaffold or surface coating to further enhance the performance of the actual electrocatalyst. Herein, the roles of Zr-MOFs in electrocatalytic processes are discussed, and some selected examples reporting the applications of Zr-MOFs in various electrocatalytic reactions, including several studies from our group, are overviewed. Challenges, limitations and opportunities in using Zr-MOFs in electrocatalysis in future studies are discussed.

Graphical abstract: Zirconium-based metal–organic frameworks and their roles in electrocatalysis

Article information

Article type
Feature Article
Submitted
09 Jun 2024
Accepted
12 Jul 2024
First published
12 Jul 2024

Chem. Commun., 2024,60, 8360-8374

Zirconium-based metal–organic frameworks and their roles in electrocatalysis

M. Tsai, K. Wu and C. Kung, Chem. Commun., 2024, 60, 8360 DOI: 10.1039/D4CC02793K

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