Issue 57, 2024

Porous organic crystals crosslinked by free-radical reactions

Abstract

Two hydrogen-bonded crosslinked organic frameworks (HCOFs) were synthesized via free radical reactions utilizing butadiene and isoprene as crosslinkers. These HCOFs exhibit high crystallinity, enabling detailed structural characterization via single-crystal X-ray diffraction analysis. Subsequently, one of the olefin-rich HCOFs was converted to a hydroxylated framework through hydroboration–oxidation while maintaining the high crystallinity.

Graphical abstract: Porous organic crystals crosslinked by free-radical reactions

Supplementary files

Article information

Article type
Communication
Submitted
20 May 2024
Accepted
12 Jun 2024
First published
24 Jun 2024
This article is Open Access
Creative Commons BY license

Chem. Commun., 2024,60, 7311-7314

Porous organic crystals crosslinked by free-radical reactions

K. Samanta, J. Mi, A. D. Chen, F. Li, R. J. Staples, A. J. Rossini and C. Ke, Chem. Commun., 2024, 60, 7311 DOI: 10.1039/D4CC02454K

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