Issue 13, 2016
From the journal:

Organic & Biomolecular Chemistry

Synthesis and absolute configuration assignment of albucidin: a late-stage reductive deiodination by visible light photocatalysis†

Hu Zhang,a   Peng-Fei Liu,a   Qiong Chen,a   Qiong-You Wu,a   Anne Seville,b   Yu-Cheng Gu,b   John Clough,b   Shao-Lin Zhoua  and  Guang-Fu Yang*a  

* Corresponding authors

a Key Laboratory of Pesticide & Chemical Biology, Ministry of Education College of Chemistry, Central China Normal University, 152 Luoyu Road, Wuhan, Hubei 430079, China
E-mail: gfyang@mail.ccnu.edu.cn

b Syngenta Jealott's Hill International Research Centre, Bracknell, Berkshire RG42 6EY, UK

Abstract

The synthesis of albucidin and its enantiomer are described. It involves a visible-light photocatalysis deiodination at the late stage. The absolute configuration of natural albucidin is determined as (1R,3S). This work provides a basis for structural modification to develop a new type of herbicidal from an old structure.

Graphical abstract: Synthesis and absolute configuration assignment of albucidin: a late-stage reductive deiodination by visible light photocatalysis

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Article information

DOI
https://doi.org/10.1039/C6OB00371K
Article type
Paper
Submitted
17 Feb 2016
Accepted
08 Mar 2016
First published
08 Mar 2016

Org. Biomol. Chem., 2016,14, 3482-3485

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Synthesis and absolute configuration assignment of albucidin: a late-stage reductive deiodination by visible light photocatalysis

H. Zhang, P. Liu, Q. Chen, Q. Wu, A. Seville, Y. Gu, J. Clough, S. Zhou and G. Yang, Org. Biomol. Chem., 2016, 14, 3482 DOI: 10.1039/C6OB00371K

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