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Issue 37, 2015
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Synthesis and characterisation of thioether functionalised gallium and indium alkoxides

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Abstract

This paper provides evidence of formerly unknown thioether coordination in metal alkoxides. The thioether functionalised alkanols serving as alcoholate ligands have been prepared by a generic route. The gallium and indium alkoxides provide the first evidence for sulphur coordination in the liquid and solid state in metal alkoxide derivatives. The presence of amines suppresses the coordination of thioether moieties leading to a well-known bonding mode in aminoalcoholates.

Graphical abstract: Synthesis and characterisation of thioether functionalised gallium and indium alkoxides

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Article information


Submitted
21 Jul 2015
Accepted
20 Aug 2015
First published
20 Aug 2015

Dalton Trans., 2015,44, 16439-16445
Article type
Paper

Synthesis and characterisation of thioether functionalised gallium and indium alkoxides

S. Barth, F. Biegger and M. Puchberger, Dalton Trans., 2015, 44, 16439
DOI: 10.1039/C5DT02777B

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