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Issue 3, 2014
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Enhanced thermal conductivity of phase change materials with ultrathin-graphite foams for thermal energy storage

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Abstract

For thermophysical energy storage with phase change materials (PCMs), the power capacity is often limited by the low PCM thermal conductivity (κPCM). Though dispersing high-thermal conductivity nanotubes and graphene flakes increases κPCM, the enhancement is limited by interface thermal resistance between the nanofillers, among other factors such as detrimental surface scattering of phonons. Here, we demonstrate that embedding continuous ultrathin-graphite foams (UGFs) with volume fractions as low as 0.8–1.2 vol% in a PCM can increase κPCM by up to 18 times, with negligible change in the PCM melting temperature or mass specific heat of fusion. The increase in κPCM, thermal cycling stability, and applicability to a diverse range of PCMs suggests that UGF composites are a promising route to achieving the high power capacity targets of a number of thermal storage applications, including building and vehicle heating and cooling, solar thermal harvesting, and thermal management of electrochemical energy storage and electronic devices.

Graphical abstract: Enhanced thermal conductivity of phase change materials with ultrathin-graphite foams for thermal energy storage

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Supplementary files

Article information


Submitted
31 Jul 2013
Accepted
18 Dec 2013
First published
23 Dec 2013

Energy Environ. Sci., 2014,7, 1185-1192
Article type
Paper
Author version available

Enhanced thermal conductivity of phase change materials with ultrathin-graphite foams for thermal energy storage

H. Ji, D. P. Sellan, M. T. Pettes, X. Kong, J. Ji, L. Shi and R. S. Ruoff, Energy Environ. Sci., 2014, 7, 1185
DOI: 10.1039/C3EE42573H

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