Issue 1, 2011
From the journal:

Chemical Communications

Synthesis and characterization of an infinite sheet of metal–alkyl bonds: unfolding the elusive structure of an unsolvated alkali-metal trisalkylmagnesiate†‡

Sharon E. Baillie,a   William Clegg,b   Pablo García-Álvarez,a   Eva Hevia,*a   Alan R. Kennedy,a   Jan Kletta  and  Luca Russob  

* Corresponding authors

a WestCHEM, Department of Pure and Applied Chemistry, University of Strathclyde, Glasgow, UK
E-mail: eva.hevia@strath.ac.uk

b School of Chemistry, Newcastle University, Newcastle upon Tyne, UK

Abstract

The study of co-complexation reactions between NaCH2SiMe3 and Mg(CH2SiMe3)2 has allowed the isolation and structural elucidation of the first solvent-free alkali-metal alkylmagnesiate [{NaMg(CH2SiMe3)3}∞] (1) as well as the related solvent-free sodium alkyl [{(NaCH2SiMe3)4}∞] (3).

Graphical abstract: Synthesis and characterization of an infinite sheet of metal–alkyl bonds: unfolding the elusive structure of an unsolvated alkali-metal trisalkylmagnesiate

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Article information

DOI
https://doi.org/10.1039/C0CC02164D
Article type
Communication
Submitted
28 Jun 2010
Accepted
20 Aug 2010
First published
31 Aug 2010

Chem. Commun., 2011,47, 388-390

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Synthesis and characterization of an infinite sheet of metal–alkyl bonds: unfolding the elusive structure of an unsolvated alkali-metal trisalkylmagnesiate

S. E. Baillie, W. Clegg, P. García-Álvarez, E. Hevia, A. R. Kennedy, J. Klett and L. Russo, Chem. Commun., 2011, 47, 388 DOI: 10.1039/C0CC02164D

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