Issue 30, 2009
From the journal:

Chemical Communications

Pseudo-allosteric regulation of the anion binding affinity of a macrocyclic coordination complex†

Junpei Kuwabara,a   Hyo Jae Yoon,a   Chad A. Mirkin,*a   Antonio G. DiPasqualeb  and  Arnold L. Rheingoldb  

* Corresponding authors

a Department of Chemistry and the International Institute for Nanotechnology, Northwestern University, 2145 Sheridan Road, Evanston, USA
E-mail: chadnano@northwestern.edu
Fax: +1 847 467 5123
Tel: +1 847 467 7302

b Department of Chemistry and Biochemistry, University of California, San Diego, 9500 Gilman Drive, La Jolla, USA

Abstract

The anion binding affinity of a macrocyclic Rh complex can be allosterically regulated by reaction with a small molecule (an isocyanide), which effects a change in macrocycle size and shape.

Graphical abstract: Pseudo-allosteric regulation of the anion binding affinity of a macrocyclic coordination complex

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Article information

DOI
https://doi.org/10.1039/B905150C
Article type
Communication
Submitted
13 Mar 2009
Accepted
04 Jun 2009
First published
19 Jun 2009

Chem. Commun., 2009, 4557-4559

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Pseudo-allosteric regulation of the anion binding affinity of a macrocyclic coordination complex

J. Kuwabara, H. J. Yoon, C. A. Mirkin, A. G. DiPasquale and A. L. Rheingold, Chem. Commun., 2009, 4557 DOI: 10.1039/B905150C

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