Issue 16, 1998

Ultra rigid cross-bridged tetraazamacrocycles as ligands—the challenge and the solution

Abstract

The challenge to metal ion binding that is represented by the proton-sponge nature of two-carbon cross-bridged tetraazamacrocycles has been overcome and a general method developed for the synthesis of their transiton, and other, metal complexes; these ultra-rigid ligands form complexes having remarkable kinetic stabilities.

Article information

Article type
Paper

Chem. Commun., 1998, 1675-1676

Ultra rigid cross-bridged tetraazamacrocycles as ligands—the challenge and the solution

T. J. Hubin, J. M. McCormick, S. R. Collinson, D. H. Busch and N. W. Alcock, Chem. Commun., 1998, 1675 DOI: 10.1039/A802060D

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