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Issue 45, 2017
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Metallocorroles as inherently chiral chromophores: resolution and electronic circular dichroism spectroscopy of a tungsten biscorrole

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Abstract

An inherently chiral metallocorrole has been resolved for the first time by means of HPLC on a chiral stationary phase. For the compound in question, a homoleptic tungsten biscorrole, the absolute configurations of the enantiomers were assigned using online HPLC–ECD measurements in conjunction with time-dependent CAM-B3LYP calculations, which provided accurate simulations of the ECD spectra.

Graphical abstract: Metallocorroles as inherently chiral chromophores: resolution and electronic circular dichroism spectroscopy of a tungsten biscorrole

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Publication details

The article was received on 16 Mar 2017, accepted on 15 May 2017 and first published on 22 May 2017


Article type: Communication
DOI: 10.1039/C7CC02027A
Chem. Commun., 2017,53, 6121-6124

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    Metallocorroles as inherently chiral chromophores: resolution and electronic circular dichroism spectroscopy of a tungsten biscorrole

    C. Schies, A. B. Alemayehu, H. Vazquez-Lima, K. E. Thomas, T. Bruhn, G. Bringmann and A. Ghosh, Chem. Commun., 2017, 53, 6121
    DOI: 10.1039/C7CC02027A

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