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Issue 10, 2016
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C–N bonded energetic biheterocyclic compounds with good detonation performance and high thermal stability

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Abstract

New C–N bonded energetic biheterocyclic compounds were synthesized using cine substitution of 1,3-dinitro-1,2,4-triazole with different energetic moieties. All the compounds were fully characterized by multinuclear NMR and infrared spectra, and elemental analyses. The structures of 4, 7, 9, and 11 were confirmed by single-crystal X-ray structure analyses. Their physicochemical properties, such as density, thermal stability and sensitivity towards impact and friction, were studied. All of the compounds have high thermal stability. The detonation properties were calculated with EXPLO5 V6.01 based on experimental densities and calculated heats of formation.

Graphical abstract: C–N bonded energetic biheterocyclic compounds with good detonation performance and high thermal stability

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Publication details

The article was received on 02 Dec 2015, accepted on 12 Feb 2016 and first published on 15 Feb 2016


Article type: Paper
DOI: 10.1039/C5TA09803C
Citation: J. Mater. Chem. A, 2016,4, 3879-3885
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    C–N bonded energetic biheterocyclic compounds with good detonation performance and high thermal stability

    Y. Tang, C. He, L. A. Mitchell, D. A. Parrish and J. M. Shreeve, J. Mater. Chem. A, 2016, 4, 3879
    DOI: 10.1039/C5TA09803C

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