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Issue 44, 2016
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Facile one-pot/one-step synthesis of heterotelechelic N-acylated poly(aminoester) macromonomers for carboxylic acid decorated comb polymers

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Abstract

Optimised monomer feed ratios in the spontaneous zwitterionic copolymerisation (SZWIP) of 2-oxazolines and acrylic acid enable the one-step synthesis of heterotelechelic α-acrylate, ω-carboxylic acid N-acylated poly(aminoester) macromonomers. Subsequent redox-initiated RAFT polymerisation at ambient temperature leads to comb polymers containing quantitative terminal side chain carboxylic acids, which allow efficient ‘grafting-onto’ using conventional peptide coupling strategies.

Graphical abstract: Facile one-pot/one-step synthesis of heterotelechelic N-acylated poly(aminoester) macromonomers for carboxylic acid decorated comb polymers

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Article information


Submitted
05 Sep 2016
Accepted
15 Oct 2016
First published
19 Oct 2016

Polym. Chem., 2016,7, 6703-6707
Article type
Communication

Facile one-pot/one-step synthesis of heterotelechelic N-acylated poly(aminoester) macromonomers for carboxylic acid decorated comb polymers

P. A. J. M. de Jongh, M. R. Bennett, G. S. Sulley, P. Wilson, T. P. Davis, D. M. Haddleton and K. Kempe, Polym. Chem., 2016, 7, 6703
DOI: 10.1039/C6PY01553K

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