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Issue 47, 2016
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Observation of the chemical reaction equilibria of element 104, rutherfordium: solid–liquid extraction of Rf, Zr, Hf and Th with Aliquat 336 resin from HCl

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Abstract

We successfully observed the equilibrium state of the chemical reactions for superheavy elements on a one-atom-at-a-time scale; we investigated the time dependence of the extraction behaviour of element 104, Rf. The distribution coefficient of Rf in 9 M HCl was found to be higher than those of its homologous elements, probably due to differences in the chloride complexation of Rf.

Graphical abstract: Observation of the chemical reaction equilibria of element 104, rutherfordium: solid–liquid extraction of Rf, Zr, Hf and Th with Aliquat 336 resin from HCl

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Publication details

The article was received on 08 Sep 2016, accepted on 01 Nov 2016 and first published on 01 Nov 2016


Article type: Communication
DOI: 10.1039/C6DT03497G
Citation: Dalton Trans., 2016,45, 18827-18831
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    Observation of the chemical reaction equilibria of element 104, rutherfordium: solid–liquid extraction of Rf, Zr, Hf and Th with Aliquat 336 resin from HCl

    T. Yokokita, Y. Kasamatsu, A. Kino, H. Haba, Y. Shigekawa, Y. Yasuda, K. Nakamura, K. Toyomura, Y. Komori, M. Murakami, T. Yoshimura, N. Takahashi, K. Morita and A. Shinohara, Dalton Trans., 2016, 45, 18827
    DOI: 10.1039/C6DT03497G

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