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Issue 32, 2016
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Metallogel formation in aqueous DMSO by perfluoroalkyl decorated terpyridine ligands

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Abstract

Terpyridine based ligands 1 and 2, decorated with a C8F17 perfluorinated tag, are able to form stable thermoreversible gels in the presence of several d-block metal chloride salts. The gel systems obtained have been characterized by NMR, X-ray diffraction, electron microscopies and Tgel experiments in order to gain insights into the observed different behaviour of the two similar ligands, also in terms of the effect of additional common anionic species.

Graphical abstract: Metallogel formation in aqueous DMSO by perfluoroalkyl decorated terpyridine ligands

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Publication details

The article was received on 19 May 2016, accepted on 14 Jul 2016 and first published on 15 Jul 2016


Article type: Paper
DOI: 10.1039/C6DT02008A
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Citation: Dalton Trans., 2016,45, 12756-12762
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    Metallogel formation in aqueous DMSO by perfluoroalkyl decorated terpyridine ligands

    R. Tatikonda, S. Bhowmik, K. Rissanen, M. Haukka and M. Cametti, Dalton Trans., 2016, 45, 12756
    DOI: 10.1039/C6DT02008A

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