Jump to main content
Jump to site search

Issue 15, 2016
Previous Article Next Article

Challenges in assignment of orbital populations in a high spin manganese(iii) complex

Author affiliations

Abstract

Magnetic, structural and computational data of four complex salts with the same mononuclear high spin octahedral Mn(III) complex cation are reported. The manifestation of Jahn–Teller-like distortions in the Mn(III) cation is dependent on the nature of the charge-balancing anion, with small anions yielding a planar elongation and large anions freezing out a preferential axial elongation along one of the amine–Mn–imine directions within that same plane. Modulation of the lattice by changing the charge balancing anion results in mixing of the orbital symmetry due to vibrational perturbation.

Graphical abstract: Challenges in assignment of orbital populations in a high spin manganese(iii) complex

Back to tab navigation

Supplementary files

Article information


Submitted
06 Oct 2015
Accepted
07 Mar 2016
First published
07 Mar 2016

Dalton Trans., 2016,45, 6702-6708
Article type
Paper
Author version available

Challenges in assignment of orbital populations in a high spin manganese(III) complex

A. J. Fitzpatrick, S. Stepanovic, H. Müller-Bunz, M. A. Gruden-Pavlović, P. García-Fernández and G. G. Morgan, Dalton Trans., 2016, 45, 6702
DOI: 10.1039/C5DT03914B

Social activity

Search articles by author

Spotlight

Advertisements