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Issue 88, 2016
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Intermetal oxygen atom transfer from an FeVO complex to a MnIII complex: an experimental and theoretical approach

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Abstract

Oxygen atom transfer (OAT) reaction between an FeVO complex and a MnIII complex resulted in the eventual formation of their corresponding FeIII and MnVO complexes. The reaction proceeded via an initial fast OAT reaction between the FeVO and MnIII complexes, yielding a half equivalent of a MnVO complex and a μ-oxo bridged FeIV dimer. The dimer regenerated the FeVO species via equilibrium, which then reacted with the remaining MnIII complex to produce another half equivalent of the MnVO complex.

Graphical abstract: Intermetal oxygen atom transfer from an FeVO complex to a MnIII complex: an experimental and theoretical approach

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Supplementary files

Article information


Submitted
01 Sep 2016
Accepted
10 Oct 2016
First published
10 Oct 2016

Chem. Commun., 2016,52, 12968-12971
Article type
Communication

Intermetal oxygen atom transfer from an FeVO complex to a MnIII complex: an experimental and theoretical approach

S. Hong, S. J. Jang, K. Cho and W. Nam, Chem. Commun., 2016, 52, 12968
DOI: 10.1039/C6CC07152J

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