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Issue 85, 2016
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Bimetallic MOFs (H3O)x[Cu(MF6)(pyrazine)2]·(4 − x)H2O (M = V4+, x = 0; M = Ga3+, x = 1): co-existence of ordered and disordered quantum spins in the V4+ system

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Abstract

The title compounds are bimetallic MOFs containing [Cu(pyz)2]2+ square lattices linked by MF6n octahedra. In each, only the Cu2+ spins exhibit long-range magnetic order below 3.5 K (M = V4+) and 2.6 K (M = Ga3+). The V4+ spins remain disordered down to 0.5 K.

Graphical abstract: Bimetallic MOFs (H3O)x[Cu(MF6)(pyrazine)2]·(4 − x)H2O (M = V4+, x = 0; M = Ga3+, x = 1): co-existence of ordered and disordered quantum spins in the V4+ system

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Publication details

The article was received on 26 Jul 2016, accepted on 27 Sep 2016 and first published on 27 Sep 2016


Article type: Communication
DOI: 10.1039/C6CC05873F
Citation: Chem. Commun., 2016,52, 12653-12656
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    Bimetallic MOFs (H3O)x[Cu(MF6)(pyrazine)2]·(4 − x)H2O (M = V4+, x = 0; M = Ga3+, x = 1): co-existence of ordered and disordered quantum spins in the V4+ system

    J. L. Manson, J. A. Schlueter, K. E. Garrett, P. A. Goddard, T. Lancaster, J. S. Möller, S. J. Blundell, A. J. Steele, I. Franke, F. L. Pratt, J. Singleton, J. Bendix, S. H. Lapidus, M. Uhlarz, O. Ayala-Valenzuela, R. D. McDonald, M. Gurak and C. Baines, Chem. Commun., 2016, 52, 12653
    DOI: 10.1039/C6CC05873F

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