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Issue 99, 2015
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Electronic vs. structural ordering in a manganese(iii) spin crossover complex

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Abstract

A symmetry breaking spin transition in a Mn(III) complex is reported with three structural phases, a high symmetry high temperature S = 2 phase, an intermediate S = 1/S = 2 ordered phase and an aperiodic low temperature phase with S = 1 cations. The aperiodicity is interpreted as resulting from long-range ordering of the NTf2 anions.

Graphical abstract: Electronic vs. structural ordering in a manganese(iii) spin crossover complex

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Article information


Submitted
22 Jun 2015
Accepted
19 Oct 2015
First published
19 Oct 2015

Chem. Commun., 2015,51, 17540-17543
Article type
Communication
Author version available

Electronic vs. structural ordering in a manganese(III) spin crossover complex

A. J. Fitzpatrick, E. Trzop, H. Müller-Bunz, M. M. Dîrtu, Y. Garcia, E. Collet and G. G. Morgan, Chem. Commun., 2015, 51, 17540
DOI: 10.1039/C5CC05129K

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