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Issue 17, 2015
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Reversible C–C coupling in phenanthroline complexes of divalent samarium and thulium

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Abstract

The reaction of a series of organolanthanide fragments of samarium and thulium with phenanthroline is reported. All adducts couple in the 4-position of the phenanthroline ligand to yield the 4–4′ dimers when they crystallize. The analysis of the solution structure revealed a thermally reversible C–C coupling in all cases.

Graphical abstract: Reversible C–C coupling in phenanthroline complexes of divalent samarium and thulium

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Supplementary files

Article information


Submitted
12 Jan 2015
Accepted
23 Jan 2015
First published
23 Jan 2015

Chem. Commun., 2015,51, 3578-3581
Article type
Communication
Author version available

Reversible C–C coupling in phenanthroline complexes of divalent samarium and thulium

G. Nocton and L. Ricard, Chem. Commun., 2015, 51, 3578
DOI: 10.1039/C5CC00289C

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