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Issue 21, 2014
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Basic isoreticular nanoporous metal–organic framework for Biginelli and Hantzsch coupling: IRMOF-3 as a green and recoverable heterogeneous catalyst in solvent-free conditions

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Abstract

The IRMOF-3 metal–organic framework (MOF) acts as a suitable green catalyst for the one-pot synthesis of dihydropyrimidinone and dihydropyridine derivatives through the Biginelli and Hantzsch reactions, and the desired products were obtained in high yields with short reaction times under mild solvent-free conditions. The MOFs can be isolated from the reaction mixture and reused.

Graphical abstract: Basic isoreticular nanoporous metal–organic framework for Biginelli and Hantzsch coupling: IRMOF-3 as a green and recoverable heterogeneous catalyst in solvent-free conditions

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Article information


Submitted
15 Nov 2013
Accepted
20 Dec 2013
First published
20 Dec 2013

RSC Adv., 2014,4, 10514-10518
Article type
Paper

Basic isoreticular nanoporous metal–organic framework for Biginelli and Hantzsch coupling: IRMOF-3 as a green and recoverable heterogeneous catalyst in solvent-free conditions

S. Rostamnia and A. Morsali, RSC Adv., 2014, 4, 10514
DOI: 10.1039/C3RA46709K

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