Jump to main content
Jump to site search

Issue 6, 2014
Previous Article Next Article

Iron-catalyzed hydrosilylation of CO2: CO2 conversion to formamides and methylamines

Author affiliations

Abstract

Catalytic hydrosilylation of CO2 is an efficient and selective approach to form chemicals. Herein, we describe the first iron catalysts able to promote the reductive functionalization of CO2 using hydrosilanes as reductants. Iron(II) salts supported by phosphine donors enable the conversion of CO2 to formamide and methylamine derivatives under mild reaction conditions.

Graphical abstract: Iron-catalyzed hydrosilylation of CO2: CO2 conversion to formamides and methylamines

Back to tab navigation

Supplementary files

Article information


Submitted
31 Jan 2014
Accepted
15 Feb 2014
First published
17 Feb 2014

Catal. Sci. Technol., 2014,4, 1529-1533
Article type
Communication
Author version available

Iron-catalyzed hydrosilylation of CO2: CO2 conversion to formamides and methylamines

X. Frogneux, O. Jacquet and T. Cantat, Catal. Sci. Technol., 2014, 4, 1529 DOI: 10.1039/C4CY00130C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.


Social activity

Search articles by author

Spotlight

Advertisements