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Issue 42, 2014
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Mechanistic insight into the hydroxylation of alkanes by a nonheme iron(v)–oxo complex

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Abstract

Hydroxylation of alkanes by a mononuclear nonheme iron(V)–oxo complex, [Fe(V)(O)(TAML)], is initiated by a rate-determining hydrogen atom (H-atom) abstraction, followed by an oxygen non-rebound process. Evidence for the H-atom abstraction–oxygen non-rebound mechanism is obtained experimentally and supported by DFT calculations.

Graphical abstract: Mechanistic insight into the hydroxylation of alkanes by a nonheme iron(v)–oxo complex

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Supplementary files

Article information


Submitted
10 Feb 2014
Accepted
28 Mar 2014
First published
31 Mar 2014

Chem. Commun., 2014,50, 5572-5575
Article type
Communication
Author version available

Mechanistic insight into the hydroxylation of alkanes by a nonheme iron(V)–oxo complex

E. Kwon, K. Cho, S. Hong and W. Nam, Chem. Commun., 2014, 50, 5572
DOI: 10.1039/C4CC01058B

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