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Issue 22, 2013
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Reactivity comparison of high-valent iron(IV)-oxo complexes bearing N-tetramethylated cyclam ligands with different ring size

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Abstract

The ring size effect of macrocyclic TMC ligands in nonheme iron(IV)-oxo complexes has been examined in hydrogen atom transfer (HAT) and oxygen atom transfer (OAT) reactions; an iron(IV)-oxo complex bearing a smaller TMC ligand is more reactive in both HAT and OAT reactions, resulting from its high FeIV/III redox potential.

Graphical abstract: Reactivity comparison of high-valent iron(iv)-oxo complexes bearing N-tetramethylated cyclam ligands with different ring size

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Publication details

The article was received on 20 Mar 2013, accepted on 28 Mar 2013 and first published on 03 Apr 2013


Article type: Communication
DOI: 10.1039/C3DT50750E
Citation: Dalton Trans., 2013,42, 7842-7845
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    Reactivity comparison of high-valent iron(IV)-oxo complexes bearing N-tetramethylated cyclam ligands with different ring size

    S. Hong, H. So, H. Yoon, K. Cho, Y. Lee, S. Fukuzumi and W. Nam, Dalton Trans., 2013, 42, 7842
    DOI: 10.1039/C3DT50750E

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