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Issue 13, 2017, Issue in Progress
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A simple synthesis method to prepare a molybdenum oxide hole-transporting layer for efficient polymer solar cells

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Abstract

We report a simple synthetic method to prepare amorphous molybdenum oxide (p-MoO3) using a favorably stable peroxomolybdic acid organosol as the precursor solution prepared by an ultrasonic reaction for the first time. The favorably smooth and dense surface morphology of the p-MoO3 layers are obtained under 150 °C thermal treatment with good optical properties and a high work function (WF) of 5.26 eV. During the annealing treatment two different oxidation states of Mo ions are observed with increasing the annealing temperature to 150 °C and 200 °C. The best performance of the P3HT:PC71BM devices with p-MoO3 anode buffer layers has been achieved under 150 °C treatment with a power conversion efficiency (PCE) of 4.02%, a VOC of 0.59 V, a JSC of 10.70 mA cm−2, and a FF of 63.7%, superior to the corresponding PEDOT:PSS modified devices. Furthermore, the performance of the PTB7:PC71BM devices with the annealed p-MoO3 buffer layers has also been dramatically improved with the best performance parameters of a PCE of 8.46%, a VOC of 0.73, a JSC of 17.02 mA cm−2, a FF of 68.1% for 150 °C. The improved performance of the devices originates from the following factors; (i) the favorable and compact surface morphology of the annealed p-MoO3 films leading to a higher rectification ratio and lower leakage current. (ii) The formation of oxygen vacancies and the growing Mo5+ cation leading to the change of WF under the annealing treatment. The highest WF of 5.26 eV for 150 °C treatment influences the built-in electric field of the devices with the photocurrent being extracted efficiently at a short-circuit.

Graphical abstract: A simple synthesis method to prepare a molybdenum oxide hole-transporting layer for efficient polymer solar cells

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Publication details

The article was received on 09 jan. 2017, accepted on 20 jan. 2017 and first published on 23 jan. 2017


Article type: Paper
DOI: 10.1039/C7RA00303J
Citation: RSC Adv., 2017,7, 7890-7900
  • Open access: Creative Commons BY-NC license
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    A simple synthesis method to prepare a molybdenum oxide hole-transporting layer for efficient polymer solar cells

    Y. Li, H. Yu, X. Huang, Z. Wu and M. Chen, RSC Adv., 2017, 7, 7890
    DOI: 10.1039/C7RA00303J

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